Electrothermally Self-Healing Delamination Cracks in Carbon/Epoxy Composites Using Sandwich and Tough Carbon Nanotube/Copolymer Interleaves.

Electrothermally Self-Healing Delamination Cracks in Carbon/Epoxy Composites Using Sandwich and Tough Carbon Nanotube/Copolymer Interleaves.
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DOI:
10.3390/polym14204313
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发表时间:
2022-10-14
期刊:
影响因子:
5
通讯作者:
Wu Z
Wu Z
中科院分区:
工程技术3区
文献类型:
--
作者:
Ouyang Q;Liu L;Wu Z

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本文提出了两种由碳纳米管(CNT)和乙烯-甲基丙烯酸共聚物(EMAA)组成的夹层多孔夹层结构,通过原位电加热CNT,可同时对碳纤维增强塑料(CFRP)层间界面进行增韧和自愈合。测量了临界应变能释放率模式I(GIC)和II(GIIC),以评估夹层的增韧和自修复效率。结果表明,与CFRP基体相比,CNT-EMAA-CNT复合材料的GIC和GIIC分别提高了24.0%和15.2%,其自修复效率分别达到109.7-123.5%和90.6-91.2%;同时,EMAA-CNT-EMAA插层可使GIC和GIIC分别提高66.9%和16.7%,GIC和GIIC的相应自愈效率分别为122.7-125.9%和93.1- 94.7%。因此,这两种插入物在层间断裂韧性上显示出良好的增韧和自愈合效率。具体地,EMAA-CNT-EMAA夹层具有更好的多功能性,即,增韧能力适中,但通过电加热的自愈合效率显著,优于传统的纯EMAA夹层和基于烘箱的加热愈合方法。
Herein, two sandwich and porous interleaves composed of carbon nanotube (CNT) and poly(ethylene-co-methacrylic acid) (EMAA) are proposed, which can simultaneously toughen and self-heal the interlaminar interface of a carbon fiber-reinforced plastic (CFRP) by in situ electrical heating of the CNTs. The critical strain energy release rate modes I (GIC) and II (GIIC) are measured to evaluate the toughening and self-healing efficiencies of the interleaves. The results show that compared to the baseline CFRP, the CNT-EMAA-CNT interleaf could increase the GIC by 24.0% and the GIIC by 15.2%, respectively, and their respective self-healing efficiencies could reach 109.7–123.5% and 90.6–91.2%; meanwhile, the EMAA-CNT-EMAA interleaf can improve the GIC and GIIC by 66.9% and 16.7%, respectively, and the corresponding self-healing efficiencies of the GIC and GIIC are 122.7–125.9% and 93.1–94.7%. Thus, both the interleaves show good toughening and self-healing efficiencies on the interlaminar fracture toughness. Specifically, the EMAA-CNT-EMAA interleaf possesses better multi-functionality, i.e., moderate toughening ability but notable self-healing efficiency via electrical heating, which is better than the traditional neat EMAA interleaf and oven-based heating healing method.
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发表时间: 2021-08-14
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