The influence of domain structure on the optical and electrical properties of transparent (Pb,La)(Mg1/3Nb2/3)O3–PbTiO3 ceramics

The influence of domain structure on the optical and electrical properties of transparent (Pb,La)(Mg1/3Nb2/3)O3–PbTiO3 ceramics
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畴结构对透明(Pb,La)(Mg1/3Nb2/3)O3—PbTiO3陶瓷光电性能的影响

DOI:
10.1016/j.ceramint.2012.10.030
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发表时间:
2013-05
影响因子:
5.2
通讯作者:
Jiangtao Zeng Guorong Li Wei Ruan Liaoying Zhen
Jiangtao Zeng Guorong Li Wei Ruan Liaoying Zhen
中科院分区:
材料科学1区
文献类型:
--
作者:
Jiangtao Zeng Guorong Li Wei Ruan Liaoying Zhen

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采用两步烧结法制备了(Pb,La)(Mg 1/3 Nb 2/3)O3-PbTiO 3(PLMNT)透明陶瓷。通过改变冷却速率,在相同成分的PLMNT透明陶瓷中形成了两种不同的畴结构。在快速冷却的样品中形成大的条状畴结构,而在缓慢冷却的样品中形成精细的指纹状畴结构。透明PLMNT陶瓷中的大畴结构引起光散射,降低了透射率。对于具有大畴结构的PLMNT陶瓷,截止波长也发生了红移,这归因于陶瓷中的内应力。不同畴结构的PLMNT陶瓷表现出不同的电学性能:与大畴结构的PLMNT陶瓷相比,细畴结构的PLMNT陶瓷具有较小的矫顽场、较大的电场诱导应变和较低的凝固温度(TVF)。
Transparent (Pb,La)(Mg1/3Nb2/3)O3–PbTiO3(PLMNT) ceramics were prepared by two stage sintering method. Two different domain structures were formed in PLMNT transparent ceramics with the same composition by changing the cooling rate. Large strip-like domain structure was formed in rapidly-cooled samples, while fine fingerprint-type domain structure was formed in slowly-cooled samples. The large domain structure in transparent PLMNT ceramics caused light scattering and decreased the transmittance. The cut-off wavelength was also red-shifted for PLMNT ceramics with large domain structure, which was attributed to the inner stress in the ceramics. PLMNT ceramics with different domain structures showed different electrical properties: Compared with PLMNT ceramics with large domain structure, PLMNT ceramics with fine domain structure had smaller coercive field, larger electric field induced strain and lower freezing temperature (TVF).
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