Time-Resolved FTIR Study on the Reaction of CHCl2 with NO2
Time-Resolved FTIR Study on the Reaction of CHCl2 with NO2
复制标题
CHCl2 与 NO2 反应的时间分辨 FTIR 研究
DOI：
10.1088/1674-0068/22/02/134-138
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发表时间：
2009-04
影响因子：
1
通讯作者：
Wu Wei-qiang
中科院分区：
文献类型：
--
作者：
Yang Chun-fan;Liu Kun-hui;*Su Hong-mei;Wang Huan;Wu Wei-qiang
The environmentally important free radical reaction of chlorinated methyl CHCl2 with NO2 was investigated by step-scan time-resolved FTIR (TR-FTIR) emission spectroscopy. Vibrationally excited products of CHClO, NO, CO, and HCl are observed in the high-resolution IR emission spectra and three possible reaction channels are therefore elucidated. In particular, the product CO is newly detected and the product HCl is identified explicitly as a yield from the CHCl2+NO2 reaction, taking advantage of the sensitive detection of HCl and CO with TR-FTIR. These results are of particular interests to understand the related realistic chemical processes including atmospheric photochemistry, biofuel combustion, waste destruction, and smoking fire.
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影响因子：
3
作者：
Jia-Xu Zhang;Zesheng Li;Jing-yao Liu;Chia-Chung Sun
通讯作者：
Jia-Xu Zhang;Zesheng Li;Jing-yao Liu;Chia-Chung Sun
DOI：
10.1021/jp8031034
发表时间：
2008-10
期刊：
The journal of physical chemistry. A
影响因子：
--
作者：
Kunhui Liu;Tiancheng Xiang;Weiqiang Wu;Shaolei Zhao;Hongmei Su
通讯作者：
Kunhui Liu;Tiancheng Xiang;Weiqiang Wu;Shaolei Zhao;Hongmei Su
影响因子：
11.4
作者：
W. Chang;S. Senkan
通讯作者：
W. Chang;S. Senkan
影响因子：
2.8
作者：
W. Tzeng;Ying-Chu Lee;S. M. Lin
通讯作者：
W. Tzeng;Ying-Chu Lee;S. M. Lin
影响因子：
1.9
作者：
W. Tsang
通讯作者：
W. Tsang