Synthesis and Characterization of a Tripodal Tris(nitroxide) Aluminum Complex and Its Catalytic Activity toward Carbonyl Hydroboration
Synthesis and Characterization of a Tripodal Tris(nitroxide) Aluminum Complex and Its Catalytic Activity toward Carbonyl Hydroboration
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三足三(硝基氧)铝配合物的合成、表征及其对羰基硼氢化反应的催化活性
DOI：
10.1021/acs.organomet.8b00933
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发表时间：
2019
期刊：
影响因子：
2.8
通讯作者：
Graves, Christopher R.
中科院分区：
文献类型：
--
作者：
Woodside, Audra J.;Smith, Mackinsey A.;Herb, Thomas M.;Manor, Brian C.;Carroll, Patrick J.;Rablen, Paul R.;Graves, Christopher R.
本文报道了一种三脚架三氮氧配体铝配合物的制备和表征。该配合物具有参与金属-配体协同催化的能力，已被用于醛和酮的硼氢化反应。这代表了地球上丰富的金属的新的过渡金属样反应性。
An aluminum complex of a tripodal tris(nitroxide)-based ligand has been prepared and characterized. The complex has the ability to participate in metal–ligand cooperative catalysis, which has been exploited for the hydroboration of both aldehydes and ketones. This represents new, transition-metal-like reactivity for an earth-abundant metal.
难以捉摸的蝎形配体：C3 对称、形式双阴离子、表面三齿配体。
影响因子：
4.6
作者：
Wei;Lan‐Chang Liang
通讯作者：
Lan‐Chang Liang
影响因子：
2.6
作者：
Thomas M. Herb;Andrew M. Poitras;K. Richardson;Bren E. Cole;Justin A. Bogart;P. Carroll;E. Schelter;C. Graves
通讯作者：
C. Graves