A Cationic N-Heterocyclic Carbene with an Organometallic Backbone: Synthesis and Reactivity
A Cationic N-Heterocyclic Carbene with an Organometallic Backbone: Synthesis and Reactivity
复制标题
具有有机金属骨架的阳离子 N-杂环卡宾：合成和反应性
DOI：
10.1021/om2004496
复制
发表时间：
2011
期刊：
影响因子：
2.8
通讯作者：
C. Ganter
中科院分区：
文献类型：
--
作者：
B. Hildebrandt;W. Frank;C. Ganter
通过将阳离子有机金属[（C5 Me 5）Ru]+片段连接到苯并咪唑阳离子上，然后将该双阳离子夹心配合物脱质子化，合成了一种新型的阳离子N-杂环卡宾配体.通过实验和理论方法研究了新卡宾的配位化学和电子性质。
A new type of cationic N-heterocyclic carbene ligand has been developed by attachment of a cationic organometallic [(C5Me5)Ru]+ fragment to a benzimidazolium cation and subsequent deprotonation of the dicationic sandwich complex. The coordination chemistry and electronic properties of the new carbene were investigated by experimental and theoretical methods.
影响因子：
8.4
作者：
Martin D;Soleilhavoup M;Bertrand G
通讯作者：
Bertrand G