Versatile structure-directing roles of deep-eutectic solvents and their implication in the generation of porosity and open metal sites for gas storage.
Versatile structure-directing roles of deep-eutectic solvents and their implication in the generation of porosity and open metal sites for gas storage.
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DOI:
10.1002/anie.200900134
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发表时间:
2009
影响因子:
16.6
通讯作者:
Bu, Xianhui
中科院分区:
文献类型:
--
作者:
Zhang, Jian;Wu, Tao;Chen, Shumei;Feng, Pingyun;Bu, Xianhui
关键词:
Trap it in and burn it out: the deep eutectic solvent provides a versatile route for the creation of highly stable porous frameworks encapsulating neutral coordinating ligand molecule, which can escape intact from the pore upon heating to directly become crystals, leaving behind permanent porosity and coordinatively unsaturated metal sites with potential applications in gas storage and catalysis.
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