Versatile structure-directing roles of deep-eutectic solvents and their implication in the generation of porosity and open metal sites for gas storage.

Versatile structure-directing roles of deep-eutectic solvents and their implication in the generation of porosity and open metal sites for gas storage.
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DOI:
10.1002/anie.200900134
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发表时间:
2009
影响因子:
16.6
通讯作者:
Bu, Xianhui
Bu, Xianhui
中科院分区:
化学1区
文献类型:
--
作者:
Zhang, Jian;Wu, Tao;Chen, Shumei;Feng, Pingyun;Bu, Xianhui

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捕获和烧掉它:深度共晶溶剂提供了一种多功能的方法来创建包裹中性配位配体分子的高度稳定的多孔骨架,这些骨架在受热时可以完整地从孔洞中逃逸出来,直接形成晶体,留下永久的孔洞和配位不饱和的金属中心,在气体存储和催化方面具有潜在的应用。
Trap it in and burn it out: the deep eutectic solvent provides a versatile route for the creation of highly stable porous frameworks encapsulating neutral coordinating ligand molecule, which can escape intact from the pore upon heating to directly become crystals, leaving behind permanent porosity and coordinatively unsaturated metal sites with potential applications in gas storage and catalysis.
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