Pt/3D-graphene/FTO electrodes: Electrochemical preparation and their enhanced electrocatalytic activity

Pt/3D-graphene/FTO electrodes: Electrochemical preparation and their enhanced electrocatalytic activity
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Pt/3D-石墨烯/FTO电极:电化学制备及其增强的电催化活性

DOI:
10.1016/j.ijhydene.2014.07.036
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发表时间:
2014-09
影响因子:
7.2
通讯作者:
Wang Guanzhong
Wang Guanzhong
中科院分区:
工程技术2区
文献类型:
--
作者:
Yang Shaolin;Huang Yongwei;Zhu Wei;Deng Bingchen;Wang Hong;Zhang Zihan;Bao Pengfei;Wang Guanzhong

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We report a facile, low-cost and green route to fabricate platinum nanoparticle (Pt NP) decorated three-dimensional (3D) graphene assembled on fluorine-doped tin oxide (FTO) electrodes (Pt/3D-G/FTO) with enhanced electrocatalytic activity. The fabrication process was accomplished by preparation of 3D graphene (3D-G/FTO) electrodes through electrochemical reduction of a graphene oxide suspension followed by electrodeposition of Pt NPs onto them. The Pt/3D-G/FTO electrode exhibits much higher catalytic activity and better stability for methanol oxidation compared with the electrodes prepared by electrodeposition of Pt NPs onto two-dimensional graphene sheets substrate (Pt/G/FTO) or bare FTO (Pt/FTO) under the same condition. These enhancements can be attributed to the high surface area, large void volume and high electrical conductivity as well as smaller size of Pt NPs in the hollows of the 3D architecture and a large amount of ridges on it.
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