Kinetics of electrochemical dechlorination of 2-chlorobiphenyl on a palladium-modified nickel foam cathode in a basic medium: From batch to continuous reactor operation
Kinetics of electrochemical dechlorination of 2-chlorobiphenyl on a palladium-modified nickel foam cathode in a basic medium: From batch to continuous reactor operation
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基本介质中钯改性泡沫镍阴极上 2-氯联苯电化学脱氯的动力学：从间歇式反应器操作到连续式反应器操作
DOI：
10.1016/j.electacta.2013.07.207
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发表时间：
2013-10
影响因子：
6.6
通讯作者：
Weiping Liu
中科院分区：
文献类型：
--
作者：
Jianmeng Chen;Shuang Song;Yanyun Qian;Weiping Liu
A kinetic model for the electrochemical dechlorination of polychlorinated biphenyls (PCBs) will be an important contribution to the design and optimization of a continuous reactor. Initially, the electrocatalytic hydrodechlorination of 2-chlorobiphenyl (2-ClBP) to biphenyl at a palladium-modified nickel foam (Pd/Ni) cathode in a batch reactor was used as a model reaction for a quantitative study of the influences of the operating parameters, including temperature, the initial concentrations of PCBs, current density and the amount of Pd loading, on the apparent reaction rate. The dechlorination was found to follow pseudo first-order kinetics with respect to the 2-ClBP concentration. It was also found that a simple global power law rate equation, with Arrhenius dependency, can be used to describe the correlation between the pseudo first-order reaction rate constants and the reaction conditions. Subsequently, a mathematical model for predicting the performance of reductive dechlorination of 2-ClBP on Pd/Ni electrodes in a continuous stirred tank reactor was constructed, based on the batch-reaction kinetics. The suitability of the model was validated by performing experiments in and out of the range of reaction conditions applied in the batch reactor. The results show that the calculated values are a good fit to the experimental data.
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影响因子：
2.9
作者：
Christian Durante;A. Isse;A. Gennaro
通讯作者：
Christian Durante;A. Isse;A. Gennaro
DOI：
10.1201/9781315139135
发表时间：
1993-12
期刊：
--
影响因子：
--
作者：
P. Brezonik
通讯作者：
P. Brezonik
影响因子：
11.4
作者：
Wang, CB;Zhang, WX
通讯作者：
Zhang, WX
DOI：
--
发表时间：
1990-08
期刊：
J. Control. Decis.
影响因子：
--
作者：
K. A. Connors
通讯作者：
K. A. Connors
影响因子：
5.3
作者：
W. Juszczyk;J. C. Colmenares;A. Śrębowata;Z. Karpiński
通讯作者：
W. Juszczyk;J. C. Colmenares;A. Śrębowata;Z. Karpiński