Zeolites in Adsorption Processes: State of the Art and Future Prospects.
Zeolites in Adsorption Processes: State of the Art and Future Prospects.
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DOI：
10.1021/acs.chemrev.2c00140
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发表时间：
2022-12-28
期刊：
影响因子：
62.1
通讯作者：
Rey, Fernando
中科院分区：
文献类型：
--
作者：
Perez-Botella, Eduardo;Valencia, Susana;Rey, Fernando
自20世纪50年代实现工业化突破以来，沸石已被广泛用作催化剂、离子交换剂和吸附剂，并在许多分离过程中继续作为最先进的吸附剂。此外，它们的特性使其成为开发和新兴分离应用的首选材料。本文旨在阐述沸石的相关性及其在吸附技术中的应用和前景。它被分为三个不同的部分，即沸石、在纳米孔材料上的吸附和沸石的化学分离。第一部分从沸石的结构、组成、制备和性能等方面对沸石进行了介绍，并简要介绍了沸石的应用。第二部分介绍了吸附科学的基本原理，特别关注了它的工业应用和我们感兴趣的案例--沸石上的吸附。最后，介绍了与化工和能源生产相关的最新分离技术，其中沸石分子筛具有实际或潜在的适用性。用沸石的优化吸附过程取代目前的一些分离方法，可能意味着在可持续性和节能方面的改进。讨论了不同的分离机制和潜在的吸附性能，使沸石对这些应用感兴趣。
Zeolites have been widely used as catalysts, ion exchangers, and adsorbents since their industrial breakthrough in the 1950s and continue to be state-of the-art adsorbents in many separation processes. Furthermore, their properties make them materials of choice for developing and emerging separation applications. The aim of this review is to put into context the relevance of zeolites and their use and prospects in adsorption technology. It has been divided into three different sections, i.e., zeolites, adsorption on nanoporous materials, and chemical separations by zeolites. In the first section, zeolites are explained in terms of their structure, composition, preparation, and properties, and a brief review of their applications is given. In the second section, the fundamentals of adsorption science are presented, with special attention to its industrial application and our case of interest, which is adsorption on zeolites. Finally, the state-of-the-art relevant separations related to chemical and energy production, in which zeolites have a practical or potential applicability, are presented. The replacement of some of the current separation methods by optimized adsorption processes using zeolites could mean an improvement in terms of sustainability and energy savings. Different separation mechanisms and the underlying adsorption properties that make zeolites interesting for these applications are discussed.
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