Mechanically Induced Light Emission and Infrared-Laser-Induced Upconversion in the Er-Doped CaZnOS Multifunctional Piezoelectric Semiconductor for Optical Pressure and Temperature Sensing

Mechanically Induced Light Emission and Infrared-Laser-Induced Upconversion in the Er-Doped CaZnOS Multifunctional Piezoelectric Semiconductor for Optical Pressure and Temperature Sensing
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用于光学压力和温度传感的掺铒 CaZnOS 多功能压电半导体中的机械诱导光发射和红外激光诱导上转换

DOI:
10.1021/acs.jpcc.5b10302
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发表时间:
2015-12
影响因子:
3.7
通讯作者:
Caofeng Pan
Caofeng Pan
中科院分区:
化学3区
文献类型:
--
作者:
Dengfeng Peng;Wei Wang;Lin Dong;Caofeng Pan

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在本研究中,我们报道了一种同时具有机械发光和上转换发光特性的掺Er四元压电半导体CaZnOS:Er~(3+)。在机械刺激下,将CaZnOS:Er3+颗粒包裹在两个聚对苯二甲酸乙二醇酯衬底之间制成的柔性薄膜,可以用肉眼观察到绿光发射。积分发射强度与施加的压力成正比,这使得CaZnOS:Er3+适合于动态压力传感应用。此外,掺杂样品还在近红外(980 Nm)激发下表现出明亮的可见光发射。Er~(3+)的2H11/2,4s3/2→4I15/2跃迁对应的两个上转换发射带之间的荧光强度比对温度变化很敏感。作为一种多功能光学材料,CaZnOS:Er3+不仅可以通过机械诱导发射来显示二维压力分布,还可以通过上转换(UC)L来传感温度。
In this study, we report an Er-doped quaternary piezoelectric semiconductor CaZnOS:Er3+ which shows both mechanoluminescence and upconversion luminescence properties. Under mechanical stimulation, green light emission can be observed by the naked eye from a flexible film fabricated by encapsulating CaZnOS:Er3+ particles between two polyethylene glycol terephthalate substrates. The integral emission intensity is proportional to applied pressure, making CaZnOS:Er3+ suitable for dynamic pressure sensing applications. Moreover, the doped sample also shows bright visible emission with near-infrared (980 nm) excitation. The fluorescence intensity ratio between two upconversion emission bands corresponding to 2H11/2, 4S3/2 → 4I15/2 transitions of Er3+ is sensitive to the variation of temperature. As a multifunctional optical material, CaZnOS:Er3+ could be used to not only visualize two-dimensional pressure distribution, through mechanically induced emission, but also sense temperature via the upconversion (UC) l...
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