Fluoride-driven 'turn on' ESPT in the binding with a novel benzimidazole-based sensor.

Fluoride-driven 'turn on' ESPT in the binding with a novel benzimidazole-based sensor.
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DOI:
10.3762/bjoc.11.61
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发表时间:
2015
影响因子:
2.7
通讯作者:
Diao S
Diao S
中科院分区:
化学4区
文献类型:
--
作者:
Liu K;Zhao X;Liu Q;Huo J;Zhu B;Diao S

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A novel fluorescence sensor (BIP) bearing NH and OH subunits displayed a highly selective and sensitive recognition property for fluoride over other anions. Fluoride-driven ESPT, poorly used in anion recognition and sensing, was suggested to be responsible for the fluorescence enhancement with a blue shift of 35 nm in the emission spectrum.
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