Graphenide Solutions: A Chemical Platform for Nanoparticle-Nanocarbon Composites.
Graphenide Solutions: A Chemical Platform for Nanoparticle-Nanocarbon Composites.
复制标题
石墨化物解决方案：纳米粒子-纳米碳复合材料的化学平台
作者：
Pénicaud
在非质子有机溶液中包含带电石墨烯层的石墨烯苯醚溶液被用作将过渡金属氧化物纳米颗粒（即镍、锰、铜和钴氧化物）接枝到碳骨架上的化学平台。还原过程是由石墨烯溶液驱动和控制的，所述石墨烯溶液产生的纳米颗粒对于所有研究的金属盐具有可比的尺寸，远低于10 nm。 该合成是通用的，并且不受金属盐类型的限制，因为还原的石墨烯层同时用作基底和还原剂。该反应是可靠的、可重复的和通用的，产生用于催化目的的材料而不需要任何种类的稳定剂或封端剂。
Graphenide solutions, comprising charged graphene layers in aprotic organic solutions, are exploited as a chemical platform to graft transition‐metal oxide nanoparticles, namely nickel, manganese, copper, and cobalt oxide, onto the carbon framework. The reduction process is driven and controlled by the graphenide solution yielding nanoparticles with comparable sizes for all studied metal salts, well below 10 nm. The synthesis is generic and is not limited by the type of metal salt, because the reduced graphene layers serve simultaneously as both substrates and reducing agents. This reaction is reliable, reproducible, and versatile, generating materials for catalytic purposes without requiring any kind of stabilization or capping agents.
登录
查看更多内容
影响因子：
--
作者：
F. Hof;Alessandro Boni;Giovanni Valenti;Kai Huang;F. Paolucci;A. Pénicaud
通讯作者：
F. Hof;Alessandro Boni;Giovanni Valenti;Kai Huang;F. Paolucci;A. Pénicaud
影响因子：
10.9
作者：
Hof, Ferdinand;Kampioti, Katerina;Penicaud, Alain
通讯作者：
Penicaud, Alain
影响因子：
16.6
作者：
Hof, Ferdinand;Bosch, Sebastian;Hirsch, Andreas
通讯作者：
Hirsch, Andreas
拉曼光谱统计 – 共价函数表征方法
影响因子：
--
作者：
Ferdinand Hof;S. Bosch;Jan M. Englert;F. Hauke;A. Hirsch
通讯作者：
A. Hirsch