Revisiting the Saito Photochemical Reduction and the Development of a One‐Pot Deoxygenation of Alcohols
Revisiting the Saito Photochemical Reduction and the Development of a One‐Pot Deoxygenation of Alcohols
复制标题
重新审视斋藤光化学还原和醇一锅脱氧的发展
DOI：
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发表时间：
2014
期刊：
影响因子：
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通讯作者：
M. Hayashi
中科院分区：
文献类型：
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作者：
R. Matsubara;Y. Shin;T. Shimada;M. Hayashi
我们重新审视了Saito光化学还原并建立了实用的反应条件，在该条件下，来自仲醇和叔醇的间-（三氟甲基）苯甲酸酯在高浓度下选择性地进行还原，以高产率提供相应的烷烃产物，而不会形成烯烃。还开发了醇类一锅脱氧为烷烃的方法。
We have revisited the Saito photochemical reduction and established practical reaction conditions, under which the reduction of m-(trifluoromethyl)benzoates, derived from secondary and tertiary alcohols, proceeds selectively at high concentration to afford the corresponding alkane products in good yields without formation of alkenes. A one-pot deoxygenation of alcohols to alkanes has also been developed.
影响因子：
9.8
作者：
Clarke, Paul A.;Santos, Soraia;Martin, William H. C.
通讯作者：
Martin, William H. C.