The fluorescence regulation mechanism of the paramagnetic metal in a biological HNO sensor.
The fluorescence regulation mechanism of the paramagnetic metal in a biological HNO sensor.
复制标题
生物 HNO 传感器中顺磁性金属的荧光调节机制
DOI:
10.1039/c5cc00787a
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发表时间:
2015-06-14
期刊:
影响因子:
--
通讯作者:
Zhang Y
中科院分区:
文献类型:
--
作者:
Yang W;Chen X;Su H;Fang W;Zhang Y
Paramagnetic metals are frequently used to regulate fluorescence emissions in chemical and biological probes. Accurate quantum calculations offer the first regulation theory that quenching is through the competitive nonradiative decay of the mixed fluorophore/metal 3ππ*/dd state isoenergetic to fluorophore-localized 1ππ* state. A theoretical model was developed to reveal the origin of paramagnetic metal induced fluorescence quenching.
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影响因子:
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