Anchorage of ASA on cellulose fibers in sizing development

Anchorage of ASA on cellulose fibers in sizing development
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浆料开发中 ASA 在纤维素纤维上的锚固

DOI:
10.3183/npprj-2015-30-04-p626-633
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发表时间:
2015-12
影响因子:
1.2
通讯作者:
Zhaoping Song
Zhaoping Song
中科院分区:
材料科学4区
文献类型:
--
作者:
Haidong Li;Wenxia Liu;Dehai Yu;Zhaoping Song

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Whether ester is formed between ASA and cellulose fibers in its sizing development is disputable. Herein, an ASA emulsion co-stabilized by polyaluminum sulfate (PAS) and Laponite particles was used to investigate the anchorage of ASA on the cellulose fibers, which can avoid the misjudgement caused by possible ester formation between ASA and cationic starch, a conventional stabilizer of ASA emulsions. Filter paper and cellulose film were sized by dipping in either acetone solution or the particle stabilized ASA emulsion. After the sized samples were characterized by infrared spectroscopy and x-ray photoelectron spectroscopy, it was found that the cellulose substrates acquired their hydrophobicity by formation of ester bonds between ASA and cellulose fibers in the absence of aluminum sulfate in both acetone and aqueous medium although the internal sizing performance of the particle stabilized ASA emulsion depended in a great extent on the employment of aluminum sulfate. The hydrolysis of ASA severely lowered the sizing performance of ASA. The occurrence of free ASA and its hydrolysis product in paper decreased the hydrophobicity of the sized paper when the particle stabilized ASA emulsion was used as a sizing agent.
DOI: --
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锂皂石和 PAS 共稳定 ASA 乳液,具有高耐水解性和施胶效率
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