Potential distribution characteristics of mild steel in seawater

Potential distribution characteristics of mild steel in seawater
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低碳钢在海水中的电位分布特征

DOI:
10.1016/j.corsci.2011.12.017
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发表时间:
2012-04
期刊:
影响因子:
8.3
通讯作者:
Kong, X. F.
Kong, X. F.
中科院分区:
材料科学1区
文献类型:
--
作者:
Zou, Y.;Wang, J.;Bai, Q.;Zhang, L. L.;Peng, X.;Kong, X. F.

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采用扫描微参比电极(SMRE)研究了低碳钢在海水中浸泡不同时间后的电位分布。对于水平浸没的试样,边缘是阴极,而中间是阳极。当垂直浸入时,试样的顶部是主阴极。经过一段时间的浸泡,底部成为主阴极。无论试样如何放置,阴极区的腐蚀产物主要为β-FeOOH和Fe 3 O 4,阳极区的腐蚀产物主要为γ-FeOOH。讨论了电位分布与腐蚀产物的关系,分析了产生这种现象的原因。
Potential distribution of mild steel immersed in seawater for various periods was investigated by SMRE (scanning micro-reference electrode). For the coupons immersed horizontally, the edge was cathode while the middle was anode. When immersed vertically, the top of the coupon was the main cathode. After a period of immersion, the bottom became the main cathode. No matter how the coupons were placed, the composition of corrosion products in the cathodic area was β-FeOOH and Fe3O4while in the anodic area was mainly γ-FeOOH. Relationship between potential distribution and corrosion products was discussed and the reasons for this phenomenon were analysed.
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