Mineral Liquid Crystals from Self-Assembly of Anisotropic Nanosystems

Mineral Liquid Crystals from Self-Assembly of Anisotropic Nanosystems
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各向异性纳米系统自组装的矿物液晶

DOI:
10.1007/3-540-36408-0_5
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发表时间:
2003
影响因子:
8.6
通讯作者:
P. Davidson
P. Davidson
中科院分区:
化学2区
文献类型:
--
作者:
J. Gabriel;P. Davidson

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本文综述了基于分子纳米线Li 2 Mo 6Se 6、纳米管Imogolite和NaNb 2 PS10、分子带状物V2 O 5、片状剥离物近晶粘土和H3 Sb 3 P2 O 14、纳米棒Boehmite(γ-AlOOH)、Akaganeite等的矿物液晶的介晶性质(β-FeOOH)、针铁矿(α-FeOOH);片状:三水铝石(Al(OH)3);盘状:Ni(OH)2;生物矿物混合物。然后,我们提出了许多阶段,可能导致新的MLC的发现。最后,我们回顾了这些中间相的性质和它们的集体行为如何被用于制造具有各向异性性质的介孔复合材料,用于制造纳米器件和太阳能电池,以及它们如何被用于允许在生物分子的NMR研究中测量残余偶极耦合。
In this article we review the mesogenic properties of the mineral liquid crystals (MLCs) based on molecular nanowires: Li2Mo6Se6; nanotubes: Imogolite and NaNb2PS10; molecular ribbons: V2O5; exfoliated single sheets: smectic clays and H3Sb3P2O14; nanorods: Boehmite (γ-AlOOH), Akaganeite (β-FeOOH ), Goethite (α-FeOOH); platelets: Gibbsite (Al(OH)3); disks: Ni(OH)2; bio-mineral hybrids. We then propose numerous phases that could lead to the discovery of new MLCs. We finally review how the properties of these mesophases and their collective behavior have been used for making mesoporous composites with anisotropic properties, for making nanodevices and solar cells, as well as how they could be used to allow the measurement of residual dipolar couplings in NMR studies of biomolecules.
生物分子的部分排列:核磁共振表征的辅助。
DOI: 10.1016/s1367-5931(00)00247-7
发表时间: 2001
影响因子: 7.8
作者:
Prestegard,JH;Kishore,AI
通讯作者: Kishore,AI