Self-healing and failure behavior of yttrium silicate coated SiCf/SiC composites in air at elevated temperatures

Self-healing and failure behavior of yttrium silicate coated SiCf/SiC composites in air at elevated temperatures
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硅酸钇涂层 SiCf/SiC 复合材料在高温空气中的自修复和失效行为

DOI:
10.1016/j.ceramint.2022.10.057
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发表时间:
2022-10
影响因子:
5.2
通讯作者:
Ning Dong
Ning Dong
中科院分区:
材料科学1区
文献类型:
--
作者:
Fang He;Yejie Cao;Yongsheng Liu;Jingxin Li;Jing Wang;Binghui Zhang;Ning Dong

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In this study, self-healing and failure behavior of yttrium silicate (YS)-coated silicon carbide fibers-reinforced silicon carbide matrix (SiCf/SiC) composites were systematically investigated at temperatures ranging from 1000 to 1400 °C for 100 h in air. The self-healing mechanism involves the filling of cracks with SiO2glass and Y2Si2O7(oxidation product). The three-point bending strength of samples before and after oxidation was determined in order to clarify the self-healing performance. The strength and strength retention of YS-coated SiCf/SiC composites after oxidation were consistently higher than those of the oxidized SiCf/SiC composites. The strength retention rate of YS-coated SiCf/SiC composites was found to be 110% at 1100 °C, while the corresponding value for SiCf/SiC composites was only 68%. According to the Deal and Grove oxidation kinetic model, the oxidation activation energy of YS-coated SiCf/SiC composites was ∼377 kJ mol−1, which is higher than that of SiCf/SiC composites (306 kJ mol−1). These results indicate that the YS coating can protect SiCf/SiC composites in oxidizing environments. Moreover, the degradation mechanisms of YS-coated SiCf/SiC composites were expounded by finite element analysis.
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