Ni-Nb-Ta bulk metallic glasses designed by a cluster-plus-glue atom model

Ni-Nb-Ta bulk metallic glasses designed by a cluster-plus-glue atom model
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采用簇加胶原子模型设计的Ni-Nb-Ta块体金属玻璃

DOI:
10.1007/s12666-011-0059-8
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发表时间:
2011-06
影响因子:
1.6
通讯作者:
Dong, C.
Dong, C.
中科院分区:
材料科学4区
文献类型:
--
作者:
Yuan, L.;Qiang, J. B.;Pang, C.;Wang, Q.;Wang, Y. M.;Dong, C.

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The formation of Ni-based ternary Ni-Nb-Ta bulk metallic glasses (BMGs) is explored in this work. Alloy compositions are designed by the cluster-plus-glue atom model based on a eutectic-related binary cluster Ni-Ni6Nb6, which is derived from the binary eutectic crystalline phase NiNb (Fe7W6type). According to the cluster-plus-glue atom model, the well-known binary BMG-forming composition Ni62Nb38can be described by a composition formula [Ni-Ni6Nb6]Ni3= Ni62.5Nb37.5. With an aim to further improve the glass-forming ability of the Ni-Nb alloy, Ta is selected as an alloying addition to partially replace Nb in the [Ni-Ni6Nb6]Ni3composition formula. The experimental results verified that BMGs with a critical size of 3 mm can be achieved at compositions [Ni-Ni6Nb6−xTax]Ni3(x = 0.9 ∼ 1.1). Thermal and mechanical properties of the obtained BMG alloys are also investigated.
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