Systematic Study of the Simple Predictive Approaches for Thermodynamic and Transport Properties of Multicomponent Solutions
Systematic Study of the Simple Predictive Approaches for Thermodynamic and Transport Properties of Multicomponent Solutions
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多组分溶液热力学和输运性质的简单预测方法的系统研究
DOI：
10.1021/ie100752w
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发表时间：
2010-07
期刊：
影响因子：
--
通讯作者：
Yan, Chuan-Wei
中科院分区：
文献类型：
--
作者：
Yang, Jia-Zhen;Liu, Jian-Guo;Tong, Jing;Guan, Wei;Fang, Da-Wei;Yan, Chuan-Wei
在 298.15 K 下测量了三元溶液 NaCl + 尿素 + H2O、五元溶液 NaCl + Na2SO4 + KCl + K2SO4 + H2O 及其二元子系统的密度、粘度和电导率。将结果与文献中报道的多组分溶液的密度、粘度和电导率一起用于研究杨氏定律对密度和电导率的预测。电导率、Patwardhan 和 Kumar 密度规则、基于 Eyring 绝对速率理论和 Patwardhan 和 Kumar 规则的混合电解质溶液粘度 Hu 方程、以及热力学和输运性质的半理想溶液理论。结果表明，所有测试的方程都可以为多组分电解质溶液的密度提供可比且准确的预测。半理想溶液理论适用于电解质和非电解质的水溶液，其对所检查溶液的密度的预测是n...
The densities, viscosities, and conductivities were measured for the ternary solution NaCl + urea + H2O, the quintuple solution NaCl + Na2SO4 + KCl + K2SO4 + H2O, and their binary subsystems at 298.15 K. The results together with the densities, viscosities, and conductivities of multicomponent solutions reported in the literature were used to study the predictability of the Young’s rule for density and conductivity, the rule of Patwardhan and Kumar for density, Hu’s equation for the viscosity of mixed electrolyte solutions based on the Eyring’s absolute rate theory and the rule of Patwardhan and Kumar, and the semiideal solution theory for thermodynamic and transport properties. The results show that all the tested equations can provide comparable and accurate predictions for the densities of multicomponent electrolyte solutions. The semiideal solution theory is applicable to the aqueous solutions of electrolytes and nonelectrolytes, and its predictions for the densities of the examined solutions are in n...
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影响因子：
1.1
作者：
J. Sangster;F. Lenzi
通讯作者：
J. Sangster;F. Lenzi
DOI：
10.1021/jp951157u
发表时间：
1996-01
期刊：
The Journal of Physical Chemistry
影响因子：
--
作者：
Donald G. Miller
通讯作者：
Donald G. Miller
DOI：
10.1021/j100890a015
发表时间：
1965-06
期刊：
The Journal of Physical Chemistry
影响因子：
--
作者：
Y. C. Wu;M. Smith;T. F. Young
通讯作者：
Y. C. Wu;M. Smith;T. F. Young
影响因子：
6.6
作者：
Hu, YF;Lee, H
通讯作者：
Lee, H
DOI：
10.1021/jp0542672
发表时间：
2006-03
期刊：
The journal of physical chemistry. A
影响因子：
--
作者：
Yu-feng Hu;S. Fan;D. Liang
通讯作者：
Yu-feng Hu;S. Fan;D. Liang