CsPbBr3/Reduced Graphene Oxide nanocomposites and their enhanced photoelectric detection application

CsPbBr3/Reduced Graphene Oxide nanocomposites and their enhanced photoelectric detection application
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CsPbBr3/还原氧化石墨烯纳米复合材料及其增强光电检测应用

DOI:
10.1016/j.snb.2017.01.168
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发表时间:
2017-06
期刊:
Sensors and Actuators B: Chemical
影响因子:
--
通讯作者:
Zhou Miao
Zhou Miao
中科院分区:
其他
文献类型:
--
作者:
Tang Xiaosheng;Zu Zhiqiang;Zang Zhigang;Hu Zhiping;Hu Wei;Yao Zhiqiang;Chen Weiwei;Li Shiqi;Han Shuai;Zhou Miao

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采用热注射法制备了CsPbBr3/还原氧化石墨烯(RGO)纳米复合材料。采用透射电子显微镜(TEM)和x射线衍射仪(XRD)对合成的CsPbBr3/RGO纳米复合材料的晶体结构和形貌进行了表征。光致发光(PL)光谱表明,与纯CsPbBr3相比,CsPbBr3/RGO纳米复合材料表现出强烈的猝灭现象,这可能是光生空穴-电子对快速分离和转移的原因。此外,CsPbBr3/RGO纳米复合材料的PL衰减结果(τave= 4.52 ns)相对于相应的CsPbBr3纳米粒子(τave= 14.72 ns)相对较短,证明了CsPbBr3纳米粒子与石墨烯之间的电荷转移。同时,CsPbBr3/RGO纳米复合材料具有较强的光响应特性,在光电探测领域具有巨大的应用潜力。
CsPbBr3/Reduced Graphene Oxide (RGO) nanocomposites were prepared by a facile hot-injection method. The crystalline structure and morphologies of the as-synthesized CsPbBr3/RGO nanocomposites were characterized by transmission electron microscopy (TEM) and X-ray diffraction (XRD). The photoluminescence (PL) spectra indicated that CsPbBr3/RGO nanocomposites displayed strong quenching phenomenon compared with the pure CsPbBr3as the probably reason of the fast separation and transfer of the photogenerated hole-electron pair. Moreover, the PL decay results of the CsPbBr3/RGO nanocomposites (τave= 4.52 ns) was relatively shorter than that of the corresponding CsPbBr3nanoparticles (τave= 14.72 ns), demonstrated the charge transfer between the CsPbBr3nanoparticles and graphene. Meanwhile, an enhanced strong photoresponse was demonstrated by the CsPbBr3/RGO nanocomposites, which showed tremendous potential applications in the field of photoelectric detection.
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