Fabrication of a Highly Stable Superhydrophobic Surface with Dual-Scale Structure and Its Antifrosting Properties

Fabrication of a Highly Stable Superhydrophobic Surface with Dual-Scale Structure and Its Antifrosting Properties
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高稳定双尺度超疏水表面的制备及其防霜性能

DOI:
10.1021/acs.iecr.6b04650
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发表时间:
2017-03
影响因子:
4.2
通讯作者:
Chen Fengqiu
Chen Fengqiu
中科院分区:
工程技术3区
文献类型:
--
作者:
Zhang Qinghua;Jim Biyu;Wang Bing;Fu Yuchen;Zhan Xiaoli;Chen Fengqiu

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采用化学腐蚀、浸涂和氟硅改性等简单工艺,制备了稳定的具有双重几何结构的超疏水铝合金表面。酸蚀和纳米二氧化硅浸渍20min的Al表面具有最好的超疏水性,其水接触角(WCas)为>157°,水滑动角(SAS)为<1°。与疏水和亲水铝表面相比,超疏水表面表现出优异的防雾、防霜和延缓结冰性能。此外,经过11次磁带测试和120厘米磨损(在0.8kpa的压力下),所制备的表面的超疏水性在机械上是持久的。纳米二氧化硅颗粒、氟硅树脂和铝表面之间强烈的界面相互作用使其具有优异的耐磨性。该方法为制备大面积超疏水铝表面提供了一条简便、低成本、稳定的工艺路线。
The stable superhydrophobic aluminum alloy surface with dual geometric architectures was prepared by a combination of simple processes of chemical etching, dip-coating, and modification of fluorosilicone. The Al surface with 20 min of acid etching and nanosilica dip-coating has the best superhydrophobicity, which showed water contact angles (WCAs) of >157° and water sliding angles (SAs) of <1°. The superhydrophobic surface showed excellent antifogging, antifrosting, and delayed icing performances, compared to hydrophobic and hydrophilic Al surfaces. Furthermore, the superhydrophobicity of as-prepared surfaces is mechanically durable after 11 tape tests and 120 cm wear (under a pressure of 0.8 kPa). The strong interfacial interactions among the SiO2 nanoparticles, fluorosilicone-modified polyester resin, and the Al surface contributed to superior abrasion resistance. This method could provide a facile, low-cost, and stable route to fabricate a large-area superhydrophobic Al surface for application in vario...
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