An extended framework of cages formed of pre-synthesised and functionalised heterometallic cages.

An extended framework of cages formed of pre-synthesised and functionalised heterometallic cages.
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由预合成和功能化的异金属笼形成的笼的扩展框架。

DOI:
10.1039/c4cc10035b
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发表时间:
2015
期刊:
Chemical communications (Cambridge, England)
影响因子:
--
通讯作者:
Whitehead GF
Whitehead GF
中科院分区:
--
文献类型:
--
作者:
Whitehead GF

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我们提出了第一个例子的扩展的3D框架合成不使用一个孤立的有机成分。这是通过在合成前分离和官能化的两个笼状络合物的组合来实现的; [nPr 2NH 2][Cr 7 NiF 8(O2 CtBu)14(O2 CC 5 H4 N)2]和[Fe 2CoO(O2 CtBu)6(HO 2CtBu)3],其中前者作为双齿连接体,桥接在后者的三个节点之间。
We present the first example of an extended 3D framework synthesised without the use of an isolable organic component. This is achieved by the combination of two cage complexes isolated and functionalised prior to synthesis; [nPr2NH2][Cr7NiF8(O2CtBu)14(O2CC5H4N)2] and [Fe2CoO(O2CtBu)6(HO2CtBu)3], where the former is as a bidentate linker, bridging between three nodes of the latter.
DOI: 10.1039/b202749f
发表时间: 2002-01-01
影响因子: 4.9
作者:
Barthelet, K;Riou, D;Férey, G
通讯作者: Férey, G