Preparation of metal-organic framework/attapulgite hybrid material for CO2 capture

Preparation of metal-organic framework/attapulgite hybrid material for CO2 capture
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用于CO2捕集的金属有机骨架/凹凸棒石杂化材料的制备

DOI:
10.1016/j.matlet.2017.02.033
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发表时间:
2017-05
期刊:
影响因子:
3
通讯作者:
Guan Guofeng
Guan Guofeng
中科院分区:
材料科学3区
文献类型:
--
作者:
Wan Hui;Que Yigen;Chen Chong;Wu Zuowang;Gu Zheng;Meng Jie;Wang Lei;Guan Guofeng

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采用原位法合成了一种新型的HKUST-1/H2O杂化材料,并将其用于CO2捕集。采用扫描电子显微镜(SEM)、X射线衍射(XRD)、热重分析(TGA)、N2吸附-脱附等温线和傅里叶变换红外光谱(FT-IR)对材料进行了表征。表征结果表明,掺入的α-Al_2O_3并没有改变HKUST-1的晶体结构和八面体几何形状。CO2吸附实验表明,与HKUST-1相比,其CO2吸附量提高了11.27%。该杂化材料优异的吸附性能和廉价的原材料使其在能源和环境领域具有潜在的应用前景。
A novel HKUST-1/attapulgite hybrid material was synthesized by in situ method for CO2capture. The materials were characterized by scanning electron microscopy (SEM), X-ray diffraction (XRD), thermo-gravimetric analysis (TGA), N2adsorption-desorption isotherm and Fourier transform infrared spectroscopy (FT-IR). The characterizations showed that the incorporation of attapulgite did not change the crystalloid structure and the octahedron geometry of HKUST-1. The CO2adsorption experiments showed an increase of 11.27% in CO2adsorption capacity compared with that of HKUST-1. The excellent adsorption capacity and the low-cost raw material made the hybrid material had potential applications in the field of energy and environment.
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