Nickel Electrodeposition on Silver for the Development of Solid Oxide Fuel Cell Anodes and Catalytic Membranes
Nickel Electrodeposition on Silver for the Development of Solid Oxide Fuel Cell Anodes and Catalytic Membranes
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镍电沉积银用于固体氧化物燃料电池阳极和催化膜的开发
DOI：
10.1149/2.1081704jes
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发表时间：
2017
影响因子：
3.9
通讯作者：
Jamil Z
中科院分区：
文献类型：
--
作者：
Jamil Z
Nickel was electrodeposited on porous Ag/GDC (silver/Ce 0.9 Gd 0.1 O 2-x) scaffolds and dense Ag/GDC composites for the fabrication of SOFC electrodes and catalytic membranes respectively. To control the distribution and amount of nickel deposition on the Ag/GDC surfaces; first, a systematic cyclic voltammetry study of nickel electrodeposition from a Watts bath on silver foils was carried out to understand the influence of operating conditions on the electrodeposition process. From the cyclic voltammetry study, it can be concluded that suitable operating conditions for nickel electrodeposition into porous Ag/GDC scaffolds and catalytic membranes are: 1.1 M Ni 2+ concentration in Watts bath; deposition potential between− 0.65 to− 1.0 V vs. Ag/AgCl; a temperature at 55 C; sodium dodecyl sulfate (SDS) as the surfactant; pH 4.0±0.2 and an agitation rate of 500 rpm. It was observed that the nickel surface microstructure changed with the deposition current densities due to the co-evolution of H 2. Pulse and continuous electrodeposition modes allow nickel to be deposited throughout porous Ag/GDC scaffolds and onto catalytic membranes. The pulse electrodeposition mode is favored as this is shown to result in an even Ni distribution within the porous scaffolds at minimum H 2 pitting.
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影响因子：
4.7
作者：
U. S. Mohanty;B. Tripathy;S. Das;Pritam Singh;V. N. Misra
通讯作者：
U. S. Mohanty;B. Tripathy;S. Das;Pritam Singh;V. N. Misra
纳米复合粉末制成的 Ni-CGO 金属陶瓷阳极：微观结构和电化学评估
DOI：
--
发表时间：
2014
期刊：
影响因子：
--
作者：
D. Macedo;F. Figueiredo;C. Paskocimas;A. Martinelli;R. Nascimento;F. Marques
通讯作者：
F. Marques
Ag/YSZ 空气阴极中的氧气渗透
DOI：
--
发表时间：
1994
期刊：
影响因子：
--
作者：
T. Kenjo;H. Takiyama
通讯作者：
H. Takiyama
影响因子：
8.3
作者：
J. R. Vilche;A. Arvia
通讯作者：
J. R. Vilche;A. Arvia
影响因子：
4.5
作者：
F. Nasirpouri;S. Janjan;S. Peighambari;M. Hosseini;A. Akbari;A. Samardak
通讯作者：
F. Nasirpouri;S. Janjan;S. Peighambari;M. Hosseini;A. Akbari;A. Samardak