Synthesis of MOF-derived nanostructures and their applications as anodes in lithium and sodium ion batteries

Synthesis of MOF-derived nanostructures and their applications as anodes in lithium and sodium ion batteries
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MOF衍生纳米结构的合成及其作为锂和钠离子电池阳极的应用

DOI:
10.1016/j.ccr.2019.02.029
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发表时间:
2019-06
影响因子:
20.6
通讯作者:
Bu Xian He
Bu Xian He
中科院分区:
化学1区
文献类型:
--
作者:
Zhong Ming;Kong Lingjun;Li Na;Liu Ying Ying;Zhu Jian;Bu Xian He

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金属有机骨架材料(MOFs)具有比表面积大、结构可调、孔结构高度有序、金属位置均匀等优点,作为制备多孔碳基材料、金属氧化物、金属碳化物、金属硫族化物、金属磷化物及其复合材料的模板材料受到了广泛关注。它也已被证明,所有这些MOF衍生的纳米结构提供了优异的性能,在电化学能量存储和转换设备中的应用,特别是在锂和钠离子电池。在MOF前驱体的热转化过程中,热解参数的选择对MOF衍生物的组成、形貌、粒径、BET比表面积等物理化学性质有着至关重要的影响。本文综述了热解温度、热解时间、热解气氛以及升温速率等热解参数对MOF衍生物物理化学性质的影响,这对MOF衍生纳米结构的可控制备具有指导意义。此外,还重点介绍了MOF衍生纳米结构作为锂、钠离子电池负极的最新研究进展,以及热解参数与MOF衍生纳米结构及锂、钠离子电池的关系。
Metal–organic frameworks (MOFs), possessing the superiorities with high surface area, tunable structure, highly ordered pores and uniform metal sites, have attracted widespread attention as promising templates for deriving various nanostructured materials, such as porous carbon-based materials, metallic oxides, metallic carbides, metallic chalcogenides, metallic phosphides, and their composites. It has also been demonstrated that all these MOF-derived nanostructures deliver excellent performances for applications in electrochemical energy storage and conversion devices, especially in lithium and sodium ion batteries. During the thermal conversion process of MOF precursors, the selection of pyrolysis parameters is of vital importance for the physicochemical properties of MOF-derived products in terms of composition, morphology, particle size, BET surface area,etc.Herein, this review summarizes the influence of pyrolysis parameters such as temperature, duration time, gas atmosphere as well as heating rate on physicochemical properties of MOF derivatives, which may provide a guidance for the controllable preparation of MOF-derived nanostructuresviathe rational parameter modulation. In addition, the timely progress of MOF-derived nanostructures as anodes in lithium and sodium ion batteries is also highlighted, and the relationship between pyrolysis parameter and MOF-derived nanostructures as well as lithium and sodium ion batteries is summarized.
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