Colloidal bismuth sulfide nanoparticles: a photoelectrochemical study of the relationship between bandgap and particle size

Colloidal bismuth sulfide nanoparticles: a photoelectrochemical study of the relationship between bandgap and particle size
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胶体硫化铋纳米粒子:带隙与粒径关系的光电化学研究

DOI:
10.1039/b311517h
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发表时间:
2004
影响因子:
--
通讯作者:
K. Wijayantha
K. Wijayantha
中科院分区:
--
文献类型:
--
作者:
D. Riley;J. Waggett;K. Wijayantha

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A method of preparing Bi2S3 nanoparticles by arrested precipitation is described. It is shown that varying the amount of stabiliser employed in the preparation controls the size of the particles. The as-prepared nanoparticles may be self-assembled on a tin oxide substrate. Photocurrent studies of the Bi2S3 modified electrode indicate that the presence of an oxidisable surface trap at approximately −0.15 V vs. Ag|AgCl|3.0 mol dm−3 NaCl. Photocurrent spectra indicate that the band edge of the Bi2S3 particles is only weakly dependent on particle size, consistent with a high effective mass of electrons in this material.