Homogeneous catalysts for CO2 hydrogenation to methanol and methanol dehydrogenation to hydrogen generation
Homogeneous catalysts for CO2 hydrogenation to methanol and methanol dehydrogenation to hydrogen generation
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CO2加氢制甲醇和甲醇脱氢制氢均相催化剂
DOI：
10.1016/j.ccr.2022.214767
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发表时间：
2022
影响因子：
20.6
通讯作者：
Himeda Yuichiro
中科院分区：
文献类型：
--
作者：
Onishi Naoya;Himeda Yuichiro
化石燃料的消耗增加了二氧化碳的排放。因此，已经积极地开发了有效减少CO2排放的方法。此外，由于化石燃料是一种有限的资源，因此有必要寻找替代碳源。甲醇是一种很有前途的化工原料和内燃机及燃料电池的燃料。CO2可作为原料与氢气反应合成甲醇，有望降低大气CO2浓度。近年来，通过甲醇脱氢产生氢的催化剂的发现已经允许甲醇合成和脱氢的组合，以促进有效的化学储氢。本文综述了近年来在CO2加氢合成甲醇和甲醇脱氢制氢反应中表现出催化活性的均相催化剂。
The consumption of fossil fuels has increased CO2emissions. Therefore, methods for effectively reducing CO2emissions have been actively developed. In addition, as fossil fuels are a limited resource, it is necessary to find an alternative carbon source. Methanol is a promising chemical raw material and fuel for internal combustion engines and fuel cells. CO2can be used as a raw material that reacts with hydrogen to synthesize methanol, which is expected to lead to a reduction in atmospheric CO2concentration. In recent years, the discovery of catalysts that generate hydrogen via the dehydrogenation of methanol has allowed the combination of methanol synthesis and dehydrogenation for facilitating efficient chemical hydrogen storage. In this paper, we summarize the homogeneous catalysts that demonstrate catalytic activity in methanol synthesis via CO2hydrogenation and the generation of hydrogen via methanol dehydrogenation.
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影响因子：
62.1
作者：
Katerina Sordakis;Conghui Tang;Lydia K. Vogt;H. Junge;P. Dyson;M. Beller;G. Laurenczy
通讯作者：
Katerina Sordakis;Conghui Tang;Lydia K. Vogt;H. Junge;P. Dyson;M. Beller;G. Laurenczy
DOI：
10.1073/pnas.0606291103
发表时间：
2006-09-26
影响因子：
11.1
作者：
Hansen, James;Sato, Makiko;Medina-Elizade, Martin
通讯作者：
Medina-Elizade, Martin
影响因子：
4.5
作者：
van de Watering, Fenna F.;Lutz, Martin;Dzik, Wojciech I.;de Bruin, Bas;Reek, Joost N. H.
通讯作者：
Reek, Joost N. H.
二氧化碳转化为甲醇：室温下的水催化方式。
影响因子：
--
作者：
Katerina Sordakis;A. Tsurusaki;Masayuki Iguchi;H. Kawanami;Y. Himeda;G. Laurenczy
通讯作者：
G. Laurenczy
影响因子：
15
作者：
Luo J;Kar S;Rauch M;Montag M;Ben-David Y;Milstein D
通讯作者：
Milstein D