Highly active palladium catalysts containing a 1,10-phenanthroline analogue N-heterocyclic carbene for room temperature Suzuki-Miyaura coupling reactions of aryl chlorides with arylboronic acids in aqueous media
Highly active palladium catalysts containing a 1,10-phenanthroline analogue N-heterocyclic carbene for room temperature Suzuki-Miyaura coupling reactions of aryl chlorides with arylboronic acids in aqueous media
复制标题
含有 1,10-菲咯啉类似物 N-杂环卡宾的高活性钯催化剂，用于水介质中芳基氯与芳基硼酸的室温 Suzuki-Miyaura 偶联反应
DOI：
10.1016/j.tetlet.2016.12.071
复制
发表时间：
2017-02
影响因子：
1.8
通讯作者：
Wang Jianhui
中科院分区：
文献类型：
--
作者：
Liu Guiyan;Liu Chengxin;Han Fangwai;Wang Zhongliang;Wang Jianhui
合成了两个新的含1,10-邻菲罗啉类似物n -杂环卡宾（NHC）的钯（II）配合物。通过1H、13C NMR和元素分析对配合物进行了表征，并通过单晶x射线衍射对其结构进行了表征。以nhc -钯配合物为催化剂，在室温条件下进行了芳氯与芳硼酸的Suzuki-Miyaura偶联反应。在低催化剂负载下，交叉偶联反应效率高
Two new palladium (II) complexes containing a 1,10-phenanthroline analogue N-heterocyclic carbene (NHC) have been synthesized. The complexes were characterized by 1H and 13C NMR spectroscopy and elemental analysis and their structures were determined by single-crystal X-ray diffraction. The NHC-palladium complexes were employed as catalysts for Suzuki-Miyaura coupling reactions of aryl chlorides with arylboronic acids in aqueous media at room temperature. The cross-coupling reactions were highly efficient with low catalysts loadings
登录
查看更多内容
影响因子：
4.9
作者：
Weibo Yang;Chongxing Liu;J. Qiu
通讯作者：
Weibo Yang;Chongxing Liu;J. Qiu
影响因子：
--
作者：
D. Catone;A. G. Guidoni;A. Paladini;S. Piccirillo;F. Rondino;M. Satta;D. Scuderi;M. Speranza
通讯作者：
D. Catone;A. G. Guidoni;A. Paladini;S. Piccirillo;F. Rondino;M. Satta;D. Scuderi;M. Speranza
影响因子：
5.2
作者：
C. So;C. Lau;F. Kwong
通讯作者：
C. So;C. Lau;F. Kwong
影响因子：
--
作者：
M. Regitz
通讯作者：
M. Regitz
影响因子：
--
作者：
S. Schneider;W. Herrmann;E. Herdtweck
通讯作者：
S. Schneider;W. Herrmann;E. Herdtweck