Unique Shear Flow Rheological Characterization of Nylon 6 and Its Nylon 610-Based Blends

Unique Shear Flow Rheological Characterization of Nylon 6 and Its Nylon 610-Based Blends
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尼龙 6 及其基于尼龙 610 的共混物的独特剪切流流变表征

DOI:
10.1080/10236660802401220
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发表时间:
2008-12
影响因子:
1.9
通讯作者:
Li, Pei-Jun
Li, Pei-Jun
中科院分区:
工程技术4区
文献类型:
--
作者:
Jiang, Cai-Yun;Wang, Da-Peng;Zhao, Shu-Gao;Li, Pei-Jun

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本文报道了对尼龙树脂,特别是尼龙6及其共混物在高剪切速率区的剪切流变特性的独特观察。我们研究的主要目的是处理尼龙熔体从Ostwald-de Wale方程的偏差,以及接受聚合物的日期。结果表明,尼龙的流变数据符合对数规律。这种独特的结果,与聚乙烯和聚丙烯的结果相反,暂时归因于尼龙熔体中氢键的断裂。
Abstract Unique observations on the shear flow rheological characterization of nylon resins, especially in the high-shear-rate region, nylon 6 and its nylon 610 blends in particular, are reported. The main aims of our study were to deal with a deviation of nylon melt from the Ostwald-de Wale equation, well accepted for polymers to date. It was found that rheological data of nylons fit well with the logarithmic law. Such unique results, in contrast to those for polyethylene and polypropylene, were tentatively attributed to the rupture of H-bonding in nylon melts.
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