Ion clustering in electrospray mass spectrometry of brine and other electrolyte solutions.
Ion clustering in electrospray mass spectrometry of brine and other electrolyte solutions.
复制标题
盐水和其他电解质溶液的电喷雾质谱中的离子簇。
DOI：
10.1039/c2cp40586e
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发表时间：
2012
期刊：
影响因子：
--
通讯作者：
D. Schröder
中科院分区：
文献类型：
--
作者：
D. Schröder
电喷雾电离被认为是研究金属盐溶液化学的一种补充技术，它使我们能够直接了解溶液中存在的分子实体。虽然在电喷雾过程中，金属离子从溶液到气相的转移与浓度、pH以及混合溶剂中的组成的显著变化有关，但对浓度系列的系统研究可以提供标准，以评估气相数据与溶液中情况的关联程度。虽然质谱学测量和溶液性质之间不存在1 ： 1的相关性，但一旦考虑到电离过程的具体情况，就可以获得非常有用的定性分子洞察和定量分析。
Electrospray ionization is suggested as a complementary technique for the investigation of the solution chemistry of metal salts, which allows us to achieve direct insight into the molecular entities present in solution. While the transfer of the metal ions from solution to the gas phase in the course of the electrospray process is associated with significant changes in concentration, pH, and also composition in the case of mixed solvents, systematic studies of concentration series can provide criteria to assess the extent to which the gas-phase data correlate with the situation in solution. While there does not exist a 1 ∶ 1 correlation between mass spectrometric measurements and solution properties, very useful qualitative molecular insights can be achieved and quantitative analysis can be made once the specific circumstances of the ionization process are taken into account.
烯丙基铟试剂的氧化态、聚集和异解离解
影响因子：
15
作者：
K. Koszinowski
通讯作者：
K. Koszinowski
影响因子：
7.4
作者：
Enke, CG
通讯作者：
Enke, CG