Construction of a novel painting system using electrodeposited SiO2 film as the pretreatment layer

Construction of a novel painting system using electrodeposited SiO2 film as the pretreatment layer
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以电沉积SiO2薄膜为预处理层的新型涂装体系的构建

DOI:
10.1016/j.corsci.2012.10.033
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发表时间:
2013-03
期刊:
影响因子:
8.3
通讯作者:
Cao, Chu-Nan
Cao, Chu-Nan
中科院分区:
材料科学1区
文献类型:
--
作者:
Zhou, Jin-He;Hu, Ji-Ming;Zhang, Jian-Qing;Cao, Chu-Nan

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本文报道了一种以电沉积二氧化硅(E-SiO_2)膜为预处理层的新型碳钢涂装系统。电沉积是基于负电位对正硅酸乙酯的溶胶-凝胶过程(水解和缩合反应)的基本催化作用。获得的高度多孔的E-SiO_2层确保了与面层的良好附着力。建立在E-SiO_2预处理层上的涂装体系,其耐蚀性能优于传统的磷化工艺。相信这种环保、低成本的预处理层可用于制备各种结构金属基材的高耐蚀涂装体系。
The present work reports a novel painting system for mild steels using electrodeposited silica (E-SiO2) film as the pretreatment layer. The electrodeposition is based on basic catalysis of sol–gel processes (hydrolysis and condensation reactions) of tetraethoxysilane by applying a negative potential. The highly porous E-SiO2layer obtained ensures good adhesion to the topcoat. The painting system constructed on E-SiO2pretreatment layer is superior in its corrosion performance to traditional phosphating process. It is believed that such environmentally friendly and low-cost pretreatment layer can be used to fabricate highly corrosion resistant painting system for a variety of structural metal substrates.
通过掺入硅烷单体降低环氧涂料的吸水率
DOI: 10.1016/j.corsci.2006.02.005
发表时间: 2006-11-01
期刊: CORROSION SCIENCE
影响因子: 8.3
作者:
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