The aqueous phase yield of alkyl nitrates from ROO + NO: Implications for photochemical production in seawater
The aqueous phase yield of alkyl nitrates from ROO + NO: Implications for photochemical production in seawater
复制标题
ROO NO 中硝酸烷基酯的水相产率：对海水中光化学生产的影响
DOI：
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发表时间：
2003
期刊：
影响因子：
--
通讯作者：
W. D. de Bruyn
中科院分区：
文献类型：
--
作者：
E. Dahl;E. Saltzman;W. D. de Bruyn
Alkyl nitrates have been observed in remote oceanic regions of the troposphere and in the surface ocean. The mechanism for their production in the oceans is not known. A likely source is the reaction of ROO + NO (where R is an alkyl group). Steady‐state laboratory experiments show that alkyl nitrates are produced in the aqueous phase via this reaction, with branching ratios of 0.23 ± 0.04, 0.67 ± 0.03, and 0.71 ± 0.04 for methyl, ethyl, and propyl nitrate respectively. The branching ratios in aqueous solution are significantly higher than in the gas phase. Irradiation of surface seawaters yield rates of alkyl nitrate production on the order of 10−18 mol cm−3 s−1, suggesting that the reaction of ROO and NO is an important source of alkyl nitrates in seawater.
影响因子：
56.9
作者：
STAMLER, JS;SINGEL, DJ;LOSCALZO, J
通讯作者：
LOSCALZO, J