Colloidal hydrophilic silicon germanium alloy nanocrystals with a high boron and phosphorus concentration shell

Colloidal hydrophilic silicon germanium alloy nanocrystals with a high boron and phosphorus concentration shell
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高硼磷壳层胶体亲水硅锗合金纳米晶

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发表时间:
2014
期刊:
影响因子:
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通讯作者:
K. Imakita
K. Imakita
中科院分区:
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文献类型:
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作者:
T. Kanno;M. Fujii;H. Sugimoto;K. Imakita

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与Si纳米晶体相比,Si 1-xGex合金纳米晶体具有潜在的上级性质,例如增强的吸收截面和更宽的带隙能量可控性。然而,关于Si 1 −xGex合金纳米晶,特别是胶体Si 1 −xGex合金纳米晶的合成报道仍然非常有限,质量也不如胶体Si纳米晶高。在这里,我们报告了一种新型的发光胶体Si 1 −xGex合金纳米晶体的直径为3至6 nm的发展。Si 1-xGex合金纳米晶体的特征在于在表面上形成高B和P浓度层。壳提供无机原子配体,并且B和P共掺杂的Si 1 −xGex纳米晶体可以分散在醇中而无需任何表面官能化过程。
Si1−xGex alloy nanocrystals potentially have superior properties compared to Si nanocrystals such as an enhanced absorption cross-section and wider controllability of the band gap energy. However, reports on the synthesis of Si1−xGex alloy nanocrystals, especially colloidal Si1−xGex alloy nanocrystals, are still very limited and the quality is not as high as that of colloidal Si nanocrystals. Here, we report the development of a new type of luminescent colloidal Si1−xGex alloy nanocrystals of 3 to 6 nm in diameter. The characteristic feature of the Si1−xGex alloy nanocrystals is the formation of a high B and P concentration layer on the surface. The shell provides inorganic atomic ligands and B and P co-doped Si1−xGex nanocrystals can be dispersed in alcohol without any surface functionalization processes.
DOI: 10.1021/nl3003254
发表时间: 2012-05-01
期刊: NANO LETTERS
影响因子: 10.8
作者:
Kwak, Jeonghun;Bae, Wan Ki;Lee, Changhee
通讯作者: Lee, Changhee