6-Chloro-N,N-Diethyl-1,3,5-Triazine-2,4-Diamine (Simazine) Electrochemical Sensing Chip Based on Biomimetic Recognition Utilizing a Molecularly Imprinted Polymer Layer on a Gold Chip

6-Chloro-N,N-Diethyl-1,3,5-Triazine-2,4-Diamine (Simazine) Electrochemical Sensing Chip Based on Biomimetic Recognition Utilizing a Molecularly Imprinted Polymer Layer on a Gold Chip
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基于金芯片上分子印迹聚合物层仿生识别的 6-氯-N,N-二乙基-1,3,5-三嗪-2,4-二胺(西玛嗪)电化学传感芯片

DOI:
10.1080/00032710802119319
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发表时间:
2008
期刊:
影响因子:
2
通讯作者:
Hiroaki Suzuki
Hiroaki Suzuki
中科院分区:
化学4区
文献类型:
--
作者:
Yusuke Fuchiwaki;R. Shoji;I. Kubo;Hiroaki Suzuki

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摘要以6-氯-N,N-二乙基-1,3,5-三嗪-2,4-二胺(西玛津)的还原电流为研究对象,研制了西玛津电化学传感芯片。为了提高西玛津传感芯片的灵敏度和选择性,采用西玛津分子印迹聚合物(MIP)对金芯片进行修饰,使其作为西玛津的仿生识别元件,并进行显示。利用西玛津传感芯片,用循环伏安法测定了西玛津的阴极电流,其峰值电流与西玛津的浓度有关。检测限为0.4 µM。西玛津传感芯片对西玛津的灵敏度是裸金电极的29倍,对西玛津的选择性比阿特拉津和MCC高。
Abstract Electrochemical sensing chip of 6-chloro-N,N-diethyl-1,3,5-triazine-2,4-diamine (Simazine) was developed on its reductive current. In order to give sensitivity and selectivity to the simazine sensing chip, a gold chip was modified with molecularly imprinted polymer (MIP) for simazine, which is worked as biomimetic recognition element and showed. Using simazine sensing chip, cathodic current of simazine was measured by cyclic voltammetry and the peak current depended on the concentration of simazine. The detection limit was 0.4 µM. Simazine sensing chip was 29 times more sensitive to simazine than bare gold electrode and showed selective response to simazine compared to atrazine and MCC, by the modification with Sim-MIP.
DOI: 10.2116/analsci.23.49
发表时间: 2007-01
影响因子: 1.6
作者:
Yusuke Fuchiwaki;A. Shimizu;I. Kubo
通讯作者: Yusuke Fuchiwaki;A. Shimizu;I. Kubo