Cooperative self-assembly of chiral L-malate and achiral succinate in the formation of a three-dimensional homochiral framework.
Cooperative self-assembly of chiral L-malate and achiral succinate in the formation of a three-dimensional homochiral framework.
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DOI：
10.1021/ic801404p
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发表时间：
2008-10-06
影响因子：
4.6
通讯作者：
Bu X
中科院分区：
文献类型：
--
作者：
Zingiryan A;Zhang J;Bu X
Chiral L-malate and achiral succinate ligands have been integrated into a three-dimensional homochiral framework by reacting transition metal cations (Mn2+), L-(-)-malic acid (L-H2ma), succinic acid (H2suc) and 4,4’-bipyridine (4,4’-bipy). Chiral L-malate bonds to Mn2+ without using -OH group, which is unusual for malate. Such unusual bonding of chiral malate results from the cooperative effect of chiral malate and achiral suc ligands during the self-assembly process, further assisted by the third complementary bipyridine ligand.
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