Anisothermal densification kinetics of the cold sintering process below 150 °C

Anisothermal densification kinetics of the cold sintering process below 150 °C
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150℃以下冷烧结过程的非等温致密化动力学

DOI:
10.1039/d0tc00395f
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发表时间:
2020
影响因子:
6.4
通讯作者:
Randall, Clive A.
Randall, Clive A.
中科院分区:
材料科学2区
文献类型:
--
作者:
Bang, Sun Hwi;Ndayishimiye, Arnaud;Randall, Clive A.

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冷烧结是一种新兴的非平衡工艺方法,其在显著降低的温度下使陶瓷粉末致密化。本研究提出了一个基本框架,研究其致密化动力学。通过控制四个致密化过程变量,包括瞬态化学,烧结温度,单轴压力和停留时间,非等温烧结动力学的高度致密化的ZnO被确定和唯象建模其相对活化能。
Cold sintering is an emerging non-equilibrium process methodology that densifies ceramic powders at significantly reduced temperatures. This study proposes a fundamental framework to investigate its densification kinetics. By controlling four densification process variables including the transient chemistry, sintering temperature, uniaxial pressure and dwell time, the anisothermal sintering kinetics of highly densified ZnO is identified and phenomenologically modeled for its relative activation energetics.
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