Transition metal salts of H4PMo11VO40 for efficient H2S removal in the liquid redox process

Transition metal salts of H4PMo11VO40 for efficient H2S removal in the liquid redox process
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H4PMo11VO40 过渡金属盐可在液体氧化还原过程中高效去除 H2S

DOI:
10.1007/s11696-016-0064-9
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发表时间:
2017-03
期刊:
影响因子:
2.2
通讯作者:
Meiqing Yu
Meiqing Yu
中科院分区:
化学4区
文献类型:
--
作者:
Yunqian Ma;Xingpeng Liu;Rui Wang;Meiqing Yu

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合成了几种过渡金属(Cu2+、Fe3+、Zn2+、Mn4+和Cr6+)H4PMo11VO40盐,并将它们的溶液用于液体氧化还原过程中的H_2S脱除。通过动态吸收实验进行了脱除硫化氢的实验。在这些多金属氧酸盐中,含Cu2+阳离子的多金属氧酸盐具有显著的脱除H_2S的性能,脱硫率可达98%。研究了相应的氧化脱硫机理和Cu2+的作用。
Several transition metal (Cu2+, Fe3+, Zn2+, Mn4+, and Cr6+) salts of H4PMo11VO40 were prepared and their solutions were used initially for H2S removal in the liquid redox process. H2S removal tests were performed by dynamic absorption experiments. Among these polyoxometalates, that with the Cu2+ cation was found to have pronounced H2S removal performance with the removal efficiency of up to 98%. The relevant oxidative desulfurization mechanism and the role of Cu2+ were studied.
Cu 和 Fe 掺杂 CsH3PMo11VO40 杂多化合物用于异丁烯醛选择性氧化成甲基丙烯酸的研究
DOI: 10.1021/ie3032718
发表时间: 2013-03
期刊: Industrial & Engineering Chemistry Research
影响因子: --
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作者:
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