Li deposited on LiCl: an efficient reducing agent

Li deposited on LiCl: an efficient reducing agent
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Li沉积在LiCl上:一种有效的还原剂

DOI:
10.1039/d0nj01010c
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发表时间:
2021
影响因子:
3.3
通讯作者:
Martin, Caleb D.
Martin, Caleb D.
中科院分区:
化学3区
文献类型:
--
作者:
Su, Xiaojun;Laperriere, Leif E.;Martin, Caleb D.

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将锂以约5%重量/重量比沉积在氯化锂粉末上。这种材料用作元素锂的来源,其优点超过块状锂替代品,包括增加质量以促进小规模反应的测量和增加表面积。该Li/LiCl材料应用于双硫代丁二烯的合成,其转化为锡醇,与商业锂颗粒相比,反应时间大幅减少,产率显著增加。
Lithium was deposited onto lithium chloride powder in a ∼5% weight/weight ratio. This material serves as a source of elemental lithium with benefits over bulk lithium alternatives including increased mass to facilitate measurement for small scale reactions and increased surface area. The Li/LiCl material is applied in the synthesis of a dilithiobutadienide that is transformed into a stannole with a drastic decrease in reaction time and notable increase in yield over commercial lithium granules.
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