Synthesis, Characterization, and Properties of the Fringy CdSe Wurtzite Nanocrystals

Synthesis, Characterization, and Properties of the Fringy CdSe Wurtzite Nanocrystals
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边缘 CdSe 纤锌矿纳米晶体的合成、表征和性能

DOI:
10.1021/jp806304r
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发表时间:
2008-10
影响因子:
3.7
通讯作者:
Jin, Baokang
Jin, Baokang
中科院分区:
化学3区
文献类型:
--
作者:
Jiang, Bangtong;Tian, Yupeng;Guo, Xiaozhu;Zhang, Shengyi;Jin, Baokang

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本文提出了一种简单的化学方法来制备片状碲化镉纤锌矿纳米晶体。该方法是以硒纳米管为模板剂,以NH3为模板剂的水热合成方法。H2O作为还原剂。通过SEM、TEM、XRD、XPS等手段对产物进行了表征。在一系列实验和表征的基础上,探讨了影响CdSe纳米晶形成的因素和机理。此外,还研究了CdSe纳米晶体的光化学、电化学和电致化学发光(ECL)性能,并获得了重要的结果。
A simple chemical method has been developed for the preparation of fringy CdSe wurtzite nanocrystals. The method is based on the template-engaged water-thermal synthesis in which the Se nanotubes were used as template reagent and NH3.H2O as reducer. The products were characterized by SEM, TEM, XRD, and XPS analyses. On the basis of a series of experiments and characterizations, the effect factors and the formation mechanism for the CdSe nanocrystals were discussed. Furthermore, the photochemical, electrochemical, and electrogenerated chemiluminescence (ECL) properties of the CdSe nanocrystals were studied and significant results were obtained.
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