Recent developments in decarboxylative cross-coupling reactions between carboxylic acids and N-H compounds.
Recent developments in decarboxylative cross-coupling reactions between carboxylic acids and N-H compounds.
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DOI：
10.1039/c9ra00929a
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发表时间：
2019-03-15
期刊：
影响因子：
3.9
通讯作者：
Vessally, Esmail
中科院分区：
文献类型：
--
作者：
Arshadi, Sattar;Ebrahimiasl, Saeideh;Hosseinian, Akram;Monfared, Aazam;Vessally, Esmail
羧酸及其衍生物是有机化学中普遍存在的化合物，在商业上具有广泛的结构多样性。近年来，在各种碳-碳和碳-杂原子交叉偶联反应中，羧酸被频繁地用作传统有机卤化物偶联伙伴的无毒和环境友好的替代品。在这条主线上，已报道了几种通过羧酸和N-H化合物之间的脱羧基交叉偶联反应合成含氮有机化合物的方法。本文重点介绍了这些反应的最新进展和发现，并着重介绍了这些反应的机理。羧酸及其衍生物是有机化学中普遍存在的化合物，在商业上具有广泛的结构多样性。
Carboxylic acids and their derivatives are ubiquitous compounds in organic chemistry, and are widely commercially available in a large structural variety. Recently, carboxylic acids have been frequently used as non-toxic and environmentally benign alternatives to traditional organohalide coupling partners in various carbon–carbon and carbon–heteroatom cross-coupling reactions. Along this line, several methods have been reported for the synthesis of nitrogen-containing organic compounds through decarboxylative cross-coupling reactions between carboxylic acids and N–H compounds. This review focuses on recent advances and discoveries on these reactions with special attention on the mechanistic aspects of the reactions. Carboxylic acids and their derivatives are ubiquitous compounds in organic chemistry, and are widely commercially available in a large structural variety.
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影响因子：
3.9
作者：
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通讯作者：
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影响因子：
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作者：
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影响因子：
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作者：
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通讯作者：
Vessally, Esmail
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作者：
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影响因子：
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作者：
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通讯作者：
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