Metal-organic coordination compounds for potential ferroelectrics

Metal-organic coordination compounds for potential ferroelectrics
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用于潜在铁电体的金属有机配位化合物

DOI:
10.1016/j.ccr.2009.02.028
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发表时间:
2009-12
影响因子:
20.6
通讯作者:
Wen Zhang
Wen Zhang
中科院分区:
化学1区
文献类型:
--
作者:
Ren-Gen Xiong;Heng-Yun Ye;Wen Zhang

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综述了近年来具有铁电性能的10个极点基团的非中心对称或同手性金属有机配位化合物(MOCC)或金属有机配位聚合物(MOCP)的合成与表征。在结构-功能关系的指导下,以同手性有机配体为构块或超分子晶体工程策略,通过协调成键,组装了一系列潜在的铁电MOCC(或MOCP)。对它们的铁电性能进行了测量和评价。展望了基于MOCCs的铁电材料的发展前景。
A summary of recent work is presented describing the synthesis and characterization of noncentrosymmetric or homochiral metal-organic coordination compounds (MOCCs) or metal-organic coordination polymers (MOCPs) which belong to 10 polar point groups with potential ferroelectric properties. Under the guidance of structure–function relationship, by using homochiral organic ligands as building blocks or supramolecular crystal engineering strategies, a series of potential ferroelectric MOCCs (or MOCPs) has been assembled through coordinating bond formation. Their ferroelectric behavior is measured and evaluated. Also the future development of ferroelectrics based on MOCCs is outlined.
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