Exploring Effective Non-metal Inorganic Cocatalysts for the Photocatalytic Conversion of CO2 Using H2O as an Electron Donor

Exploring Effective Non-metal Inorganic Cocatalysts for the Photocatalytic Conversion of CO2 Using H2O as an Electron Donor
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探索有效的非金属无机助催化剂,以水为电子供体光催化转化二氧化碳

DOI:
10.1021/acsaem.2c01865
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发表时间:
2022
影响因子:
6.4
通讯作者:
Kentaro*
Kentaro*
中科院分区:
材料科学3区
文献类型:
--
作者:
Xu;Xuanwen; Asakura;Hiroyuki; Hosokawa;Saburo; Tanaka;Tsunehiro*; Teramura;Kentaro*

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我们考察了一系列非金属无机助催化剂,它们在以水为电子给体的情况下,对CO的光催化转化具有良好的析CO选择性。各种含有Si、Ga、Mg、Zn的非金属无机助催化剂能提高CO的生成速率。尤其是表面高度分散的锌基化合物,如氢氧化锌、硅酸锌和氧化锌,在这些助催化剂中表现出最好的性能。锌基化合物中的反阴离子影响助催化剂的性能,包括活性和稳定性。
We have surveyed a wide range of non-metal inorganic cocatalysts showing good selectivity toward CO evolution for the photocatalytic conversion of CO2using H2O as an electron donor. A variety of non-metal inorganic cocatalysts containing Si, Ga, Mg, and Zn enhance the formation rate of CO. In particular, Zn-based compounds, such as Zn(OH)2, ZnSiO3, and ZnGa2O4, that are highly dispersed on the surface exhibit the best performance among these cocatalysts. The counter anions in the Zn-based compounds influence the cocatalyst properties, including activities and stabilities.
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