Effect of carbonization temperature on the structure and microwave absorbing properties of hollow carbon fibres

Effect of carbonization temperature on the structure and microwave absorbing properties of hollow carbon fibres
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碳化温度对中空碳纤维结构及吸波性能的影响

DOI:
10.1016/j.ceramint.2011.02.017
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发表时间:
2011-08
影响因子:
5.2
通讯作者:
Long, Chunguang
Long, Chunguang
中科院分区:
材料科学1区
文献类型:
--
作者:
Xie, Wei;Cheng, Haifeng;Chu, Zengyong;Chen, Zhaohui;Long, Chunguang

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通过在氮气中在550至950 °C范围内的温度下碳化聚丙烯腈(PAN)中空固化纤维1小时来制备一系列聚丙烯腈基中空碳纤维(PAN-HCF)。研究了炭化温度对PAN高导电性纤维的结构、元素组成、表面电导率、电磁参数和反射率的影响。结果表明,所制备的PAN-HCF未发生石墨化,碳含量和表面电导率随炭化温度的升高而增加。当碳化温度为750 °C时,PAN-HCF/树脂复合材料在6.06 GHz处的反射率为−7.50 dB,反射率低于−5 dB的频段为6 GHz。
A series of polyacrylonitrile-based hollow carbon fibres (PAN-HCFs) were prepared by carbonizing polyacrylonitrile (PAN) hollow cured fibres at temperature ranging from 550 to 950 °C for 1 h in nitrogen. The effects of carbonization temperature on the structure, elemental compositions, surface electrical conductivity, electromagnetic parameters and reflectivity of PAN-HCFs were investigated. Results indicate that the obtained PAN-HCFs have not been graphitized and the C content and surface electrical conductivity increases as the carbonization temperature increases. The reflectivity of composites of PAN-HCFs and resin is −7.50 dB at 6.06 GHz and the band of the reflectivity under −5 dB is 6 GHz when the carbonization temperature is 750 °C.
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期刊: Carbon
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