Synthesis and field-emission properties of novel hierarchical ZnO hexagonal towers

Synthesis and field-emission properties of novel hierarchical ZnO hexagonal towers
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新型分级ZnO六方塔的合成及场发射性能

DOI:
10.1016/j.jallcom.2012.04.003
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发表时间:
2012-08
影响因子:
6.2
通讯作者:
Guoqing.Miao
Guoqing.Miao
中科院分区:
材料科学2区
文献类型:
--
作者:
Lili.Wu;Hong.Gao;E.Zhang;Guoqing.Miao

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通过在前驱体中添加微量Fe粉作为催化剂,首次采用化学气相沉积法制备了新型的分级ZnO六角塔。扫描电子显微镜图像表明,新型分级ZnO六角塔的外表面是逐层组装的。X射线衍射分析表明,ZnO六方塔结构优先沿[0001]方向沿着生长。在室温下观察到以380nm为中心的强紫外发射。并对其场发射特性进行了研究。由于新颖的层结构和高的晶体质量,获得了2.37Vμm− 1的低开启电场和约2691的高场增强因子。这种分级结构的ZnO微结构可以作为高性能场发射器件的候选材料。
Novel hierarchical ZnO hexagonal towers were fabricated via chemical vapor deposition for the first time by adding trace Fe power in the precursor as a catalyst. The scanning electron microscopy images showed that the outside surface of novel hierarchical ZnO hexagonal towers was layer-by-layer assembly. X-ray diffraction pattern indicated that the hierarchical ZnO hexagonal towers grew preferentially along the [0001] direction. Intense UV emission centered at 380nm was observed at room temperature. Moreover, their field-emission properties were studied. A low turn-on electric field of 2.37Vμm−1and high field enhancement factor of about 2691 were obtained, due to the novel layer structure and high crystalline quality. This kind of hierarchical ZnO microstructures could be a good candidate for high performance field emission devices.
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