Intermediates involved in the two electron reduction of NO to N2O by a functional synthetic model of heme containing bacterial NO reductase.
Intermediates involved in the two electron reduction of NO to N2O by a functional synthetic model of heme containing bacterial NO reductase.
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DOI:
10.1021/ja807700n
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发表时间:
2008-12-10
影响因子:
15
通讯作者:
Solomon EI
中科院分区:
文献类型:
--
作者:
Collman JP;Dey A;Yang Y;Decréau RA;Ohta T;Solomon EI
Reaction of a functional biferrous heme/nonheme model complex at low temperature leads to the formation of a distal nonheme nitrosyl followed by a trans heme nonheme bis-nitrosyl intermediate. The EPR and Raman data on this intermediate indicate that the two nitrosyl centers are close. This complex gives off N2O and provides support for the trans mechanism proposed for NOR enzymes.
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