Water Solubilization Capacity and Volume-Induced Percolation of Sodium Bis(2-ethylhexyl)sulfosuccinate Microemulsions in the Presence of 1-Alkyl-3-Methylimidazolium Chloride Ionic Liquids

Water Solubilization Capacity and Volume-Induced Percolation of Sodium Bis(2-ethylhexyl)sulfosuccinate Microemulsions in the Presence of 1-Alkyl-3-Methylimidazolium Chloride Ionic Liquids
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1-烷基-3-甲基咪唑氯化物离子液体存在下双(2-乙基己基)磺基琥珀酸钠微乳液的水增溶能力和体积诱导渗滤

DOI:
10.1021/je2006506
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发表时间:
2011-08
影响因子:
--
通讯作者:
Ren, Qilong
Ren, Qilong
中科院分区:
工程技术3区
文献类型:
--
作者:
Wei, Junjie;Su, Baogen;Yang, Jiexin;Xing, Huabin;Bao, Zongbi;Yang, Yiwen;Ren, Qilong

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研究了氯离子型离子液体(emimCl、bmimCl和omimCl)存在下丁二酸二(2-乙基己基)酯磺酸钠(AOT)在异辛烷微乳液中的增溶能力.水增溶能力在低IL浓度下增强,但在高IL浓度下降低。同时,在低浓度下,随着离子液体链长的增加,其增溶水能力增加。研究了离子液体对AOT微乳液体积诱导逾渗的影响。对于微乳液,随着分散相体积分数(Φ)的增加,在高浓度IL时没有渗流现象,而在低浓度IL时出现渗流电导,且渗流阈值(Φp)随IL浓度的增加而增大。对于含IL的微乳液,
The water solubilization capacity of sodium bis(2-ethylhexyl)sulfosuccinate (AOT) in isooctane microemulsions in the presence of chloride anion-based ionic liquids (ILs), such as 1-ethyl-3-methylimidazolium chloride (emimCl), 1-butyl-3-methylimidazolium chloride (bmimCl), and 1-octyl-3-methylimidazolium chloride (omimCl), was investigated. The water solubilization capacity is enhanced at low IL concentrations but decreases at high concentrations of IL. Meanwhile, the water solubilization capacity increases with the increase of chain length of ILs at low IL concentrations. The effect of ILs on the volume-induced percolation of AOT microemulsions was also studied. For the microemulsions, with an increasing volume fraction of dispersed phase (Φ), no percolation phenomena can be observed at high concentrations of IL, whereas the percolation conductance occurs at low IL concentrations and the percolation threshold (Φp) increases with the increase of IL concentrations. For the IL-containing microemulsions, the ...
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