Reactions of a P N stabilised aluminium dihydride with ruthenium hydride complexes
Reactions of a P N stabilised aluminium dihydride with ruthenium hydride complexes
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P N 稳定的二氢化铝与氢化钌配合物的反应
DOI:
10.1016/j.poly.2023.116531
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发表时间:
2023
期刊:
影响因子:
2.6
通讯作者:
Pécharman A
中科院分区:
文献类型:
--
作者:
Pécharman A
Treatment of [Ru(L)(PPh3)2(CO)H2] (L = PPh3, IMes; IMes = 1,3-bis(2,4,6-trimethylphenyl)imidazol-2-ylidene) with anN-mesityl amidophosphine aluminium dihydride complex (Al(Psingle bondN)H2) gives [Ru(PPh3)2(CO)H3{Al(Psingle bondN)H}] (2) and [Ru(IMes)(PPh3)(CO)H3{Al(Psingle bondN)H}] (4), which are present in solution as mixtures of diastereomers. Crystal structure determinations and density functional theory (DFT) calculations suggest both2and4can be formulated as [Ru(L)(PPh3)(CO)H3][Al(Psingle bondN)H] complexes with bridging hydride ligands.
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DOI:
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发表时间:
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期刊:
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