Highly size- and shape-controlled synthesis of silver nanoparticles via a templated Tollens reaction.
Highly size- and shape-controlled synthesis of silver nanoparticles via a templated Tollens reaction.
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DOI:
10.1002/smll.201101474
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发表时间:
2012-03-12
期刊:
影响因子:
13.3
通讯作者:
Burley, Glenn A.
中科院分区:
文献类型:
--
作者:
Dondi, Ruggero;Su, Wu;Griffith, Gerry A.;Clark, Graham;Burley, Glenn A.
A mild, facile one-step synthetic strategy for the preparation of size-and shape-controlled silver nanoparticles (AgNPs) is presented. The high degree of size-and shape-control of these AgNPs is achieved by the use of triazole sugar ligands scaffolded by a central resorcinol ether core. Both the triazoles and the resorcinol ether core mediate the nucleation, growth, and passivation phases of the preparation of AgNP in the presence of the Tollens reagent as the silver source. Kinetic and 1H NMR titration data is presented describing the nature of the interactions between the Tollens reagent and these ligands.
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