Materials Formed by Combining Inorganic Glasses and Metal-Organic Frameworks.
Materials Formed by Combining Inorganic Glasses and Metal-Organic Frameworks.
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DOI：
10.1002/chem.202200345
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发表时间：
2022-07-06
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影响因子：
--
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在这里，我们提出了玻璃或结晶金属有机框架（mof）与无机玻璃的结合，以创建新的混合复合材料和混合物。这种新的复合方法背后的动机是改善mof的可加工性问题和机械性能，同时保持其普遍存在的特性。本文提出了MOF和玻璃MOF与无机玻璃成功复合形成和配对的规律。重点还放在这些材料的合成路线以及在其生产和表征方面预期的挑战。根据其化学性质，材料可分为结晶MOF -玻璃复合材料和混合物。此外，考虑了这两类材料的潜在特性和应用，主要目的是保留两种成分的有益特性，同时规避各自的缺点。这篇概念文章探讨了通过化学上通用的功能性金属有机框架（MOF）家族与无处不在、低成本和耐用的无机玻璃的结合，形成新型杂化复合材料。由这种组合产生的混合物和复合材料可以最大限度地减少并最终解决mof的成本、耐用性和可加工性问题，同时保留其宝贵的性能。
Here, we propose the combination of glassy or crystalline metal‐organic frameworks (MOFs) with inorganic glasses to create novel hybrid composites and blends.The motivation behind this new composite approach is to improve the processability issues and mechanical performance of MOFs, whilst maintaining their ubiquitous properties. Herein, the precepts of successful composite formation and pairing of MOF and glass MOFs with inorganic glasses are presented. Focus is also given to the synthetic routes to such materials and the challenges anticipated in both their production and characterisation. Depending on their chemical nature, materials are classified as crystalline MOF‐glass composites and blends. Additionally, the potential properties and applications of these two classes of materials are considered, the key aim being the retention of beneficial properties of both components, whilst circumventing their respective drawbacks. The formation of novel hybrid composites through the combination of the chemically versatile and functional metal‐organic framework (MOF) family, with ubiquitous, low cost and durable inorganic glasses is explored in this Concept article. The blends and composites created from this combination may serve to minimise, and eventually solve cost, durability and processability issues of MOFs, whilst retaining their valuable properties.
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影响因子：
15
作者：
Hou, Jingwei;Rios Gomez, Maria Laura;Bennett, Thomas D.
通讯作者：
Bennett, Thomas D.
影响因子：
3.5
作者：
Le, Quyen Huyen;Palenta, Theresia;Wondraczek, Lothar
通讯作者：
Wondraczek, Lothar
DOI：
10.3390/ma11020326
发表时间：
2018-02-24
期刊：
Materials (Basel, Switzerland)
影响因子：
--
作者：
Drago L;Toscano M;Bottagisio M
通讯作者：
Bottagisio M
影响因子：
4.6
作者：
Fulchiron R;Belyamani I;Otaigbe JU;Bounor-Legaré V
通讯作者：
Bounor-Legaré V
影响因子：
15
作者：
Ashling, Christopher W.;Johnstone, Duncan N.;Bennett, Thomas D.
通讯作者：
Bennett, Thomas D.